Product ID:ECCOSPRAY 122S
MSDS Date:11/13/1990
FSC:8030
NIIN:00N038717
MSDS Number: BRGBG

EMERSON & CUMING INC

77 DRAGON CT
WOBURN, MA 01888
US

Emergency Phone: 617-935-4850;617-938-8630

Info Phone: 617-828-3300

Cage: DO244

EMERSON & CUMING INC DIV/W R GRACE CO

AUOBURN, MA 01888 US

Telephone: (617) 935-4850 OR (617) 938-8630

Cage: DO244

METHANE, DICHLORO-; (METHYLENE CHLORIDE)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 50-60%

OSHA PEL 500 PPM; 1000, C

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHANE, DICHLORODIFLUORO-; (FREON 12)

CAS: 75-71-8

RTECS: PA8200000

Fraction By Weight: 30-45%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SILICONE RESIN

Fraction By Weight: <5%

& COULD HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS

RTECS: 9999999ZZ

LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY

RTECS: 9999999ZZ

INTO CONTRS. SCRUB AREA W/SOAPY WATER & RINSE.

RTECS: 9999999ZZ

CONC TO PREVENT LOCAL BUILDUP OF VAPOR.

RTECS: 9999999ZZ

CHLORIDES, FLUORIDES .

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: VAPS MAY CAUSE IRRIT TO
RESP TRACT, & MAY EXERT NARC/ANESTH EFTS. MAY BE FATAL IF
CONCENTRATED VAP ARE INHALED DIRECTLY FROM AEROSOL CONTR. EYE: SEV
IRRIT UPON DIRECT CONT. SKIN: IRRIT U PON DIRECT CONT. PRLNGD EXPOS
MAY RSLT IN DEFAT DERM. INGEST: HARMFUL IF SWALLOWED. CHRONIC:
SEVERAL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: GP2B(IARC), IARC
MNGRPH VOL SUP 7M P 194, 1987 ANTIC TO BE A CARCIN(NTP 6TH ANN RPT
(SUM), 199133333
Effects of Overexposure:HLTH HAZ:CHRONIC INHAL STUDIES RPTD BY NIOSH
REVEALED THAT TEST ANIMALS EXPOSED TO METHYLENE CHLORIDE CONC AS
HIGH AS 10,000 PPM SHOWED SLIGHT LIVER & KIDNEY CHANGES. WHEN
ADMINSTERED VIA INHAL TO ANI MALS IN LAB TESTS, METHYLENE CHLORIDE
OVEREXP RSLTD IN INCR INCIDENCES OF BRONCHIAL & LIVER CARCINOMAS.
(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: REMOVE TO FRESH AIR. GIVE ARTIFICAL RESPIRATION IF NOT
BREATHING. GIVE OXYGEN IF BREATHING DIFFICULT. GET IMMEDIATELY
MEDICAL ATTENTION. EYE: IMMEDIATELY FLUSH W/WATER FOR @ LST 15 MIN;
GET MED ICAL ATTENTION. SKIN: 'EMOVE CONTAMINATED CLOTHING. WASH
AFFECTED AREA WITH SOAP AND WATER. INGEST: DILUTE WITH LARGE QTY OF
WATER. GET IMMEDIATE MEDICAL ATTENTION.

Flash Point:NON-FLAMMABLE
Extinguishing Media:WATER FOG.
Fire Fighting Procedures:NIOSH/MSHA APPRVD PRESS DEMAND SCBA & FULL
PROT EQUIP. IF LARGE QTY OF MATERIAL ARE INVOLVED, EVACUATE AREA
AND FIGHT FIRE FROM A SAFE DISTANCE.
Unusual Fire/Explosion Hazard:TOX VAPS MAY BE EVOLVED UPON EXPOS TO
HEAT/OPEN FLAME. EXPOS TO HEAT MAY RSLT IN EXPLOS RUPTURING OF
SCALED AEROSOL CONTRS. THERMAL DECOMP PROD MAY (SUPP DATA)

Spill Release Procedures:FOR SM SPILLS: IF AEROSOL CANS ARE PUNCTURED,
TURN ON ALL VENT EQUIP TO EVAC VAPS. EVAC IMMED AREA WHILE
PROPELLANT & SOLV IS ALLOWED TO EVAP. ABSORB RESIDUAL MATL W/SAND,
VERMICULITE/OTHER ABSORB MAT . SCRAPE/SHOVEL ABSORBED WASTE &
ABSORB(ING 6)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY PLACE; KEEP REMOVED
FROM ANY HEAT OR OPEN FLAME. KEEP AWAY FROM HEAT, SPARKS, OPEN
FLAME.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES/HOT SURFACES. HEAT &/OR UV
RADIATION MAY CAUSE FORMATION OF CHLORIDES, FLUORIDES, AND/OR
PHOSGENE .

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:DO NOT BREATHE VAPS. USE ONLY W/PROPER MECH EXHAUST VENT.
FLEXIBLE DUCTWORK SHOULD EXTEND TO AREAS OF HIGH (ING 7)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:INCL CHLORIDES, FLUORIDES .EFTS OF OVEREXP: CAUTION: CNTNS
METHYLENE CHLORIDE. USE ONLY IN OPEN SPACES W/ADEQ VENT. PRLNGD
BRTHG OF HIGH CONC OF VAPS IN CONFINED SPACES MAY LEAD TO LOS S OF
CONSCIOUSNESS/ASPHY. CHLOROFLUOROCARBON MATLS HAVE PRDCD SENSIT OF
MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS (ING 4)

Boiling Pt:B.P. Text:<75F,<24C
Vapor Pres:>3@25C
Vapor Density:LTR/AIR
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS AEROSOL SPRAY
Percent Volatiles by Volume:>90

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, CHEMICALLY ACTIVE METAL POWDERS (ALUMINUM,
MAGNESIUM/POTASSIUM, LITHIUM). MAY REACT VIOLENTLY ON CONT.
Stability Condition to Avoid:EXPOSURE TO HEAT &/OR OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. MAY
EMIT HIGHLY TOX ORGANOFLUORIDES & PHOSGENE UPON THERMAL DECOMP.
(ING 8)

Waste Disposal Methods:SPILLED MATL & WAST RINSES ARE CLASSIFIED AS
CHEM WASTE, & MUST BE DISPOSED OF I/A/W LOCAL, STATE, & FED REGS.
DO NOT INCINERATE EMPTY /UNUSED CONTR-DISPOSE OF EXPIRED MATLS AS A
NONFLAMM AEROSOL I/A/ W CURRENT LOCAL, STATE, & FEDERAL
REGULATIONS.

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particular situation.